Search results for "quantum [effect]"
showing 10 items of 5105 documents
Intersystem crossing in Fe(II) coordination compounds
1994
Fe(II) spin-crossover systems can be quantitatively converted from the low-spin (LS) to the high-spin (HS) state well below the thermal transition temperature by irradiating either into the metal-ligand charge transfer or d-d absorption bands, and even in low-spin systems a transient population of the HS state can be achieved. This fact can be made use of to determine HS → LS relaxation rate constants for a wide variety of Fe(II) spin-crossover and low-spin systems. The HS → LS relaxation shows strong deviations from an Arrhenius behaviour, with nearly temperature-independent tunnelling below ∼70 K and a thermally activated process above ∼100 K. The range of more than 12 orders of magnitude…
A theoreticalab initiostudy on the H2NO + O3reaction
2003
The deviation of the NH2 pseudo-first-order decay Arrhenius plots of the NH2 + O3 reaction at high ozone pressures measured by experimentalists, has been attributed to the regeneration of NH2 radicals due to the subsequent reactions of the products of this reaction with ozone. Although these products have not yet been characterized experimentally, the radical H2NO has been postulated, because it can regenerate NH2 radicals through the reactions: H2NO + O3 NH2 + O2 and H2NO + O3 HNO + OH + O2. With the purpose of providing a reasonable explanation from a theoretical point of view to the kinetic observed behaviour of the NH2 + O3 system, we have carried ab initio electronic structure calculat…
A Contradiction between Pulsed and Steady-State Studies in the Recombination Kinetics of Close Frenkel Defects in KBr and KCl Crystals
1994
Theoretical study of the kinetics of the correlated annealing of pairs of close (geminate) F-H centers in KCl and KBr crystals controlled by their diffusion and elastic attraction shows that the multi-step (kink) decay in defect concentrations observed more than once in thermostimulated experiments takes place only for very close F-H center pairs which are no further than fourth nearest neighbors. On the other hand, it is demonstrated (both theoretically and experimentally) that such F-H center pairs should be destroyed by the tunneling recombination already at time ≤10 -4 s, i.e. much before beginning of the thermostimulated experiments. Possible explanations of this contradiction are sugg…
Statistical modeling, simulation, and experimental verification of wideband indoor mobile radio channel
2018
This paper focuses on the modeling, simulation, and experimental verification of wideband single-input single-output (SISO) mobile fading channels for indoor propagation environments. The indoor reference channel model is derived from a geometrical rectangle scattering model, which consists of an infinite number of scatterers. It is assumed that the scatterers are exponentially distributed over the two-dimensional (2D) horizontal plane of a rectangular room. Analytical expressions are derived for the probability density function (PDF) of the angle of arrival (AOA), the PDF of the propagation path length, the power delay profile (PDP), and the frequency correlation function (FCF). An efficie…
Minidisk dynamics in accreting, spinning black hole binaries: Simulations in full general relativity
2021
We perform magnetohydrodynamic simulations of accreting, equal-mass binary black holes in full general relativity focusing on the impact of black hole spin on the dynamical formation and evolution of minidisks. We find that during the late inspiral the sizes of minidisks are primarily determined by the interplay between the tidal field and the effective innermost stable orbit around each black hole. Our calculations support that a minidisk forms when the Hill sphere around each black hole is significantly larger than the black hole's effective innermost stable orbit. As the binary inspirals, the radius of the Hill sphere decreases, and minidisk sconsequently shrink in size. As a result, ele…
Astrophysics with the Laser Interferometer Space Antenna
2023
Full list of authors: Amaro-Seoane, Pau; Andrews, Jeff; Sedda, Manuel Arca; Askar, Abbas.; Baghi, Quentin; Balasov, Razvan; Bartos, Imre; Bavera, Simone S.; Bellovary, Jillian; Berry, Christopher P. L.; Berti, Emanuele; Bianchi, Stefano; Blecha, Laura; Blondin, Stephane; Bogdanovic, Tamara; Boissier, Samuel; Bonetti, Matteo; Bonoli, Silvia; Bortolas, Elisa; Breivik, Katelyn; Capelo, Pedro R.; Caramete, Laurentiu; Cattorini, Federico; Charisi, Maria; Chaty, Sylvain; Chen, Xian; Chruslinska, Martyna; Chua, Alvin J. K.; Church, Ross; Colpi, Monica; D'Orazio, Daniel; Danielski, Camilla; Davies, Melvyn B.; Dayal, Pratika; De Rosa, Alessandra; Derdzinski, Andrea; Destounis, Kyriakos; Dotti, Massi…
Relativistic simulations of black hole-neutron star coalescence: the jet emerges
2014
We perform magnetohydrodynamic simulations in full general relativity (GRMHD) of a binary black hole-neutron star on a quasicircular orbit that undergoes merger. The binary mass ratio is 3:1, the black hole initial spin parameter $a/m=0.75$ ($m$ is the black hole Christodoulou mass) aligned with the orbital angular momentum, and the neutron star is an irrotational $\Gamma=2$ polytrope. About two orbits prior to merger (at time $t=t_B$), we seed the neutron star with a dynamically weak interior dipole magnetic field that extends into the stellar exterior. At $t=t_B$ the exterior has a low-density atmosphere with constant plasma parameter $\beta\equiv P_{\rm gas}/P_{\rm mag}$. Varying $\beta$…
Dark coupling and gauge invariance
2010
We study a coupled dark energy–dark matter model in which the energymomentum exchange is proportional to the Hubble expansion rate. The inclusion of its perturbation is required by gauge invariance. We derive the linear perturbation equations for the gauge invariant energy density contrast and velocity of the coupled fluids, and we determine the initial conditions. The latter turn out to be adiabatic for dark energy, when assuming adiabatic initial conditions for all the standard fluids. We perform a full Monte Carlo Markov Chain likelihood analysis of the model, using WMAP 7-year data.
Future CMB cosmological constraints in a dark coupled universe
2010
Cosmic microwave background satellite missions as the ongoing Planck experiment are expected to provide the strongest constraints on a wide set of cosmological parameters. Those constraints, however, could be weakened when the assumption of a cosmological constant as the dark energy component is removed. Here we show that it will indeed be the case when there exists a coupling among the dark energy and the dark matter fluids. In particular, the expected errors on key parameters as the cold dark matter density and the angular diameter distance at decoupling are significantly larger when a dark coupling is introduced. We show that it will be the case also for future satellite missions as EPIC…
Binary neutron star mergers: a jet engine for short gamma-ray bursts
2016
We perform magnetohydrodynamic simulations in full general relativity (GRMHD) of quasi-circular, equal-mass, binary neutron stars that undergo merger. The initial stars are irrotational, $n=1$ polytropes and are magnetized. We explore two types of magnetic-field geometries: one where each star is endowed with a dipole magnetic field extending from the interior into the exterior, as in a pulsar, and the other where the dipole field is initially confined to the interior. In both cases the adopted magnetic fields are initially dynamically unimportant. The merger outcome is a hypermassive neutron star that undergoes delayed collapse to a black hole (spin parameter $a/M_{\rm BH} \sim 0.74$) imme…